Let denote the matrix (Loewner order). Most the following inequalities apply to more general linear operators.

Basic inequalities

As you’d expect, there are matrix versions of the Markov and Chebyshev inequalities. A good overview is given in Appendix C here: https://arxiv.org/pdf/quant-ph/0012127

Markov

For matrix and PSD ,

Of course, this reduces to usual Markov inequality (basic inequalities:Markov’s inequality).

Chebyshev

Markov’s inequality extends to Chebyshev’s inequality in the same way as in the scalar case:

A Chernoff-like inequality

For matrix , symmetric matrix and matrix such that where is the conjugate transpose of , we have

We can prove this easily using Markov’s inequality:

Here we’ve used that the exponential of the zero matrix is the identity. Note also that since the trace is a linear operator, so